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35.3.2 Galvanic Corrosion and Protection When two dissimilar metals are electrically connected and both are exposed to the same environment, the more active metal will be attacked at a faster rate than if there had been no electrical connection between the two. Similarly, the less active metal will be protected or suffer less attack because the surface areas of both metals can be used to dissipate the electrons generated by oxidation of the more active metal. The net flow of electrons from the more active to the less active metal increases the attack rate of the more active metal and decreases that of the less active metal. An adverse area ratio is characterized by having a larger surface area of less active metal than that of the more active metal. Cracks in a barrier protective coating (i.e., polymers) applied to the more active metal in a galvanic-couple situation can create an extremely adverse area ratio, resulting in rapid localized attack in the cracks. The standard electromotive force (emf) series of metals (Table 35.1) lists

metals in order of increasing activity, starting with gold (Au), which is the least active. If two of the metals listed were joined in a galvanic couple, the more active one would be attacked and plating or deposition of the less active one would occur. This is based on the fact that solutions contain only unit activity (concentration) of ions of each of the two metals. The standard EMF series is valid only for pure metals at 25 C and in equilibrium with a solution containing unit activity (concentration) of its own ions. If ion concentrations are greater than unit activity, the potentials are more positive; if less, the opposite is true.

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Alter Procedure prSpellNumber -- demo of use of Automation objects @mnsAmount money, @chvAmount varchar(500) output, @debug int = 0 As set nocount on Declare @intErrorCode int, @intObject int, -- hold object token @bitObjectCreated bit, @chvSource varchar(255), @chvDesc varchar(255) Select @intErrorCode = @@Error If @intErrorCode = 0 exec @intErrorCode = sp_OACreate 'DjnToolkit.DjnTools', @intObject OUTPUT

The database combines three types of information, general business data, waste compositions, and waste disposal rates All the information is based on the 38 business SIC code groupings Most of the data was collected as part of a 1999 California Statewide Waste Characterization Study Overall 1200 businesses in California were studied covering all SIC code groupings The Indiana Institute on Recycling (wwwindstateedu/recycle/), a state agency, was created in 1989 by the General Assembly of Indiana and is located at Indiana State University The institute developed concepts, methods, and procedures for assisting Indiana residents and businesses in reducing and recycling solid waste One aspect of this involved site visits to companies in Indiana to aid them directly in reducing their solid waste stream and increasing recycling The institute has placed 80 case studies documenting this work on their web site (wwwindstateedu/recycle/caselisthtml).

Downloaded from Digital Engineering Library @ McGraw-Hill (www.digitalengineeringlibrary.com) Copyright 2004 The McGraw-Hill Companies. All rights reserved. Any use is subject to the Terms of Use as given at the website.

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The galvanic series (Table 35.2) shows a similar relationship, except that impure metals such as alloys are also included and the medium is seawater. Other media, other concentrations, and other temperatures can further alter the order of the list. Therefore, care should be exercised in applying these data to a given galvanic corrosion situation except as a general, loose guide.

Many of these case studies included waste generating and recycling details for each company are described in each case study Bene ts of this data source are the ease of collection and a relatively high amount of data (80 case studies) The case studies also provided contact information, which could be used for clari cation or additional information A drawback of this data source, and a potential source of error, is that it was collected by another agency Their full methodologies and accuracy level were not completely described in the case studies In all 80 businesses were studies by the institute, covering 23 SIC code groupings The Wisconsin Department of Natural Resources has also conducted case study research in a similar manner to the Indiana Institute of Recycling The Wisconsin Department of Natural Resources has conducted 52 waste reduction case studies covering 18 SIC code groupings (wwwdnrstatewi.

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